Photoredox Catalysts

No.	Photoredox Catalyst	Local $\lambda_{max}$ (nm)	*E $_{red}$ (V vs SCE)	E $_{red}$ (V vs SCE)	*E $_{o x}$ (V vs SCE)	E $_{o x}$ (V vs SCE)	Product Number	Reference for catalyst properties	Reference for catalyst use
1	Ru(bpy) $_{3}$ $_{2}$	452	0.77	-1.33	-0.81	1.29	754730	Chem. Rev. 2013, 113, 5322	Science 2008, 322, 77
2	[Ru(phen) $_{3}$ ]Cl $_{2}$ •H $_{2}$ O	422	0.82	-1.36	-0.87	1.26	343714	Chem. Rev. 2013, 113, 5322	Nature 2011, 480, 224
3	[Ru(bpm) $_{3}$ ]Cl $_{2}$	454	0.99	-0.91	-0.21	1.69	747785	Chem. Rev. 2013, 113, 5322	Chem. Sci. 2012, 3, 2807
4	Ru(bpz) $_{3}$ $_{2}$	443	1.45	-0.8	-0.26	1.86	747777	Chem. Rev. 2013, 113, 5322	J. Am. Chem. Soc. 2011, 133, 19350
5	fac-Ir(ppy) $_{3}$	375	0.31	-2.19	-1.73	0.77	694924	Chem. Rev. 2013, 113, 5322	Nature Chem. 2012, 4, 85
6	fac-Ir(dFppy) $_{3}$	346	0.77	-2	-1.46	1.29	900540	Inorg. Chem. Front. 2014, 1, 562, J. Am. Chem. Soc. 2003, 125, 7377	Nature 2011, 480, 224
7	[Ir(dmppy) $_{2}$ (dtbbpy)]PF $_{6}$	--	0.55	-1.52	-0.87	1.21	N/A	J. Am. Chem. Soc. 2014, 136, 6858	J. Am. Chem. Soc. 2014, 136, 6858
8	[Ir(ppy) $_{2}$ (dtbbpy)]PF $_{6}$	380	0.66	-1.51	-0.96	1.21	747769	Chem. Rev. 2013, 113, 5322	J. Am. Chem. Soc. 2013, 135, 17735
9	[Ir(Fmppy) $_{2}$ (dtbbpy)]PF $_{6}$	--	0.77	-1.5	-0.94	1.33	N/A	Chem. Mater. 2005, 17, 5712	Chem. Mater. 2005, 17, 5712
10	[Ir(dF(Me)ppy) $_{2}$ (dtbbpy)]PF $_{6}$	360	0.97	-1.44	-0.92	1.49	901409	Chem. Mater. 2005, 17, 5712, Inorg. Chem. 2011, 50, 11514	Science 2017, 355, 727
11	[Ir(dFppy) $_{2}$ (dtbbpy)]PF $_{6}$	365	1.14	-1.42	-0.96	1.6	901368	J. Organo. Met. Chem. 2015, 776, 51, J. Mater. Chem. C 2016, 4, 3726, J. Am. Chem. Soc. 2016, 138, 13862	J. Am. Chem. Soc. 2016, 138, 13862
12	[Ir[dF(CF $_{3}$ )ppy] $_{2}$ (dtbbpy)]PF $_{6}$	380	1.21	-1.37	-0.89	1.69	747793	Chem. Rev. 2013, 113, 5322, Chem. Mater. 2005, 17, 5712	Science 2014, 345, 437
13	[Ir[dF(CF $_{3}$ )ppy] $_{2}$ (bpy)]PF $_{6}$	379	1.32	-1.37	-1	1.69	804215	Inorg. Chem. Front. 2014, 1, 562	Science 2014, 345, 433
14	[Ir[dF(CF $_{3}$ )ppy] $_{2}$ (5,5'-dCF $_{3}$ -bpy)]PF $_{6}$	--	1.68	-0.69	-0.43	1.94	N/A	Nature 2016, 539, 268	Nature 2016, 539, 268
15	Cr(Ph $_{2}$ phen) $_{3}$ $_{3}$	300-400	1.4	-0.27	--	--	N/A	Angew. Chem. Int. Ed. 2015, 54, 6506	Angew. Chem. Int. Ed. 2015, 54, 6506
16	Rose Bengal [RB-Na $_{2}$ ] (T1)	549	0.81	-0.99	-0.96	0.84	330000	Chem. Rev. 2016, 116, 10075	Green Chem. 2012, 14, 1293
17	Eosin Y [EY-Na $_{2}$ ] (T1)	520	0.83	-1.08	-1.15	0.76	E4382	Chem. Rev. 2016, 116, 10075	Adv. Synth. Catal. 2015, 357, 2050
18	Rhodamine 6G [Rh6G] (S1)	530	1.18	-1.14	-1.09	1.23	252433	Chem. Rev. 2016, 116, 10075	J. Am. Chem. Soc. 1969, 6, 251
19	Rhodamine B [RhB] (S1)	550	1.26	-0.96	-1.31	0.91	83689	Chem. Rev. 2016, 116, 10075	Synlett 2015, 26, 265
20	9,10-Dicyanoanthracene [DCA]	422	1.99	-0.91	--	--	459852	Chem. Rev. 2016, 116, 10075	J. Am. Chem. Soc. 1988, 110, 3677
21	1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene [4CzIPN]	435	1.35	-1.21	-1.04	1.52	901817	ACS Catal. 2016, 6, 873	ACS Catal. 2016, 6, 873
22	Mes-(MeO)4Acr-Ph-Bf $_{4}$	412	1.62	-0.84	--	--	900693	J. Org. Chem. 2016, 81, 7244	J. Org. Chem. 2016, 81, 7244
23	Mes-(MeO)4Acr-Ar-Bf $_{4}$ , Ar = 3,5-dimethoxyphenyl	414	1.65	-0.82	--	--	900694	J. Org. Chem. 2016, 81, 7244	J. Org. Chem. 2016, 81, 7244
24	Mes-Acr-Me-Bf $_{4}$	425	2.08	-0.57	--	--	794171	Chem. Rev. 2016, 116, 10075	J. Am. Chem. Soc. 2013, 135, 9588
25	Mes-(t-Bu)2Acr-Ph-Bf $_{4}$	420	2.08	-0.59	--	--	900421	J. Org. Chem. 2016, 81, 7244	Science 2015, 349, 1326
26	Mes-Me2Acr-Ph-Bf $_{4}$	438	2.09	-0.58	--	--	793876	Nature Chem. 2014, 6, 720, Acc. Chem. Res. 2016, 49, 1997	Nature Chem. 2014, 6, 720
27	Mes-Acr-Ph-Bf $_{4}$	432	2.17	-0.5	--	--	793221	Nature Chem. 2014, 6, 720, Acc. Chem. Res. 2016, 49, 1997	Org. Lett. 2015, 17, 1316
28	2,4,6-tris(4-methoxyphenyl) pyrylium-Bf $_{4}$ [p-MeO-TPT]	470	1.84	-0.5	--	--	900692	Chem. Ber. 1993, 126, 1671	Chem. Sci. 2013, 4, 2625
29	2,4,6-tri-p-tolylpyrylium-Bf $_{4}$ [p-Me-TPT]	444	2.13	-0.42	--	--	900685	Chem. Ber. 1993, 126, 1671	J. Am. Chem. Soc. 2015, 137, 15684
30	2,4,6-Triphenylpyrylium-Bf $_{4}$ [TPT]	416	2.39	-0.27	--	--	272345	Chem. Ber. 1993, 126, 1671	Chem. Ber. 1993, 126, 1671
31	10-Phenylphenothiazine [PTh]	<300	--	--	-2.1	0.68	903167	Chem. Rev. 2016, 116, 10075	J. Am. Chem. Soc. 2014, 136, 16096

¶ Photoredox Catalysts

¶ Photoredox Catalyst References and Properties